Yeah, foam anything is absolutely verboten if you need high dielectric strength.
More than likely, good quality solid PE (good) or PTFE (better) dielectric cable will have more than adequate dielectric strength here, but note that breakdown is almost entirely the result of voids, moisture ingress, cracks or other defects in the insulation, and not the thickness of the insulation itself (PE has a dielectric strength of ~20kV per mm while PTFE is around 60kV/mm).
Usually the dielectric strength for coax assumes RF rather than DC and so some allowance is made for dielectric heating, in which case PE is far inferior to PTFE. Of course, it never hurts to actually test samples of cable for breakdown using a current-limited HV power supply; that's what I would do if I planned on exceeding the datasheet ratings here.