Yep, shoulder washers, or if you need a larger fastener than you can find a suitable shoulder washer for, a regular plastic spacer on the shank of the bolt and a plastic or fiber washer on each side would do. If the OD of the plastic spacer is close to or larger than the OD of the head/nut then you might want metal washers on top of the insulating ones to spread the clamping forces out past the spacer. For heavy loads, you'd want to use heavy structural washers rather than plain flat washers.
Be aware that plastics can flow under compressive loads, so you may not be able to rely on bolt tension alone to keep the fastening secure with plastic washers. In those cases you probably want a nylon insert or deformed thread locknut to keep it from coming loose, and/or Belleville washers to maintain tension. It all depends on the materials, environment, and geometry involved.
This all assumes a dry environment, though, if this will be outdoors or otherwise exposed to water then you might need to take extra precautions to ensure that water can't get into the fastening and form an internal conductive part, or can't bead up across the insulating washers