From my post of 2020 about determining outside foil with a DE-5000.
A quantitative measurement. I take advantage of the three-terminal measurement (high, low, and guard) capability of the DE-5000 LCR meter. The capacitor being measured is a 715P (originally Sprague, then SBE and Vishay, since sold to CDE), which is film-foil construction, single unit. The value is 100 nF, 600 V. The manufacturer did not mark the "outside foil", nor specify it on the data sheet. (I have an extensive collection of polypropylene capacitors, both film-foil and metallized film, but could not find one with the old bar marking the outside foil.) I therefore arbitrarily marked the ends "1" and "2" before the measurement. The capacitor is about 0.6" diameter, 1.2" long, with 1.0" lead spacing. I wrapped a piece of 0.5" wide copper tape around the midsection, with a tab sticking out for the test connection.
Here are the tabulated values, all measured at 10 kHz.
DE-5000
Red 2 1 Cu Cu 1 2
Black 1 2 2 1 Cu Cu
Guard Cu Cu 1 2 2 1
C 99.38 nF 99.38 nF 4.1 pF 25 pF 17 pF 2 pF
Q > 1000 > 1000 22 75 14 very low
Obviously, "1" is the outside foil, showing roughly 20 pF to the copper tape. I made no effort to control the stray capacitance at the pF level, so the small capacitances vary. The low Q of the small capacitances results partly from the mediocre dielectric constant of the epoxy shell.