I've had luck printing on the opposite side of A4 sheet transparencies with a colour laser printer, then using thin double-sided adhesive. Shiny appearance, any graphics you want, users can't scratch/abrade the colour (it's on the side stuck to the device) and easy to do in small volumes.
Does this suit what you want to do at all?
Various thoughts:
* If you're sticking to a dark coloured panel: you may want to paint the rear of the transparency white (after printing on it and before adding adhesive)
* If you need silver: either paint silver on after printing or aim to stick onto an aluminium panel
* Spraypaints
might be too agressive chemically, don't know have not tried. Traditional acrylics + an airbrush are a possible alternative.
* You have to mirror your image before printing
* I use inkscape to draw my stuff, I'm very familiar with it. Anything will do.
* Spray adhesive might work instead of thin double-sided
* Attach the double-sided adhesive
before you cut/trim the decals. Keep the backing paper on so you don't foul your scissors.
* For larger scale batches: vinyl/sticker cutters would be useful.
* EDIT: my laser printer is on old drums + old toner so it prints a bit thin now. A printer that has a 'toner density' control would be useful to counteract this opacity loss (mine doesn't)
* EDIT2: I've heard of 'light' coloured toners in the printing world. Probably prohibitively expensive and only for specific printers however, but a curiosity nonetheless.