I assume you've got the typical preamp output with some opamp or discrete circuit, a 50 ohm stabilization resistor and an AC coupling cap. The 50 ohms here has nothing to do with impedance matching or RF concerns, it just insures stable operation with cable capacitance. I see values of anywhere between 10 and 600 ohms, though 50 and 100 seem most common. In the history of audio I doubt a cap has ever been damaged by an ESD event short of a lightening strike. I'd never add protection. As for the coupling cap, though film is preferred, as long as the electrolytic is large enough, and remember it's likely in series with a similar cap in the power amp, you won't get distortion. The usual rule is 10X the value for the desired -3dB point, effectively a couple Hz.