Temporarily wrap 10 turns of insulated wire around the toroid, apply mains to the primary winding, and measure the 10 turn winding (leaving the existing 27V winding unconnected). Divide by 10 to get a volts/turn value.
Now you can use the volts/turn to dial any voltage you may need.
If there is enough room, you don't even have to unwind the 27V winding; just leave it unconnected.
Do you know the power rating (in VA) of the transformer?
If so, just make sure that any/all new secondary (or secondaries combined) don't exceed the VA (ie. the wire diameter chosen amp carrying capability multiplied by the voltage).
If not, use the diameter of the existing 27V wire as a rough approximation of the current capability (lookup dia->amp in table and multiply by 27V to get VA).
If your new secondary is wound to produce less voltage, you can increase its diameter proportionally to give more current.