First, burn that app note. It is so full of wrong information that will lead you astray. For instance, you can NOT use PFD II without an active filter, but Figs. 12, 14 and 15 suggest you can.
For your question, which is actually more like three

Broadcast FM is 88...108 MHz and what you normally do is to use a tuner that brings the modulation frequency down to a fixed IF, mostly 10.7 MHz.
This is done by mixing the desired received signal with a local oscillator (LO) operating with an offset of 10.7 MHz. So your LO would either operate over 77.3...97.3 or 98.7...118.7 MHz.
This LO is today almost always a PLL controlled synthesizer for digital tuning. Channel spacing is 50 kHz, which is what both the 4046 and HC4046 PFD can handle. Obviously, the VCO will not work, you need an external VCO.
The demodulation at 10.7 MHz is the second PLL circuit, and neither 4046 or HC4046 will be up to this. Look for specific FM demodulator chips instead. Search for "quadrature demodulator".