I figured it was "No". Just rolling ideas.
From guessing about the "power drop of invertor" thing, maybe you want sometimes 240VAC, sometimes 24VDC, on the same conductors? Is this what you mean, nothing about offsetting the AC?
That is an option. Has it's own safety issues.
In fairness it's probably not worth bothering. For 6Amp 240VAC I can use much, much cheaper cable. I can simply add another 3 core (2mm^2) 13amp outdoor cable up the same route and cable tie it to the original. It's black cable, black ties, back of the house.
All this is intended to be off grid. I just want to power a few things off it. Ideally an office set up of circa 200-500W for a few hours a day maybe.
In another thread I have a schematic of the circuit. The inverter is earthed, fused and the output passes via an RCD etc.
In the UK house insurance covers you for accidental damage. Unless you delibrately set your house on fire (arson), it would be difficult to argue negligence on the consumer side. Tampering with the mains installation wiring (anything that needs unscrewed!), might find you partly liable. This will not touch the mains wiring, save for a protective earth tap. It will power only one extension.