Hey everyone, thank you for the input.
I would be more comfortable with 2 10uF footprints and again, 50v is kind of low if you think someone's gonna use 24v or more as input voltage.
Makes sense to use higher voltage rating for the capacitors. Anyhow, if external supply is used (not via USB-C), then I expect additional capacitors on the carrier board. The board I am working on, is a breakout board for the RP2040 (I know there are many, but I have my reasons).
And, would I not violate the USB Spec in terms of maximum input capacitance if I use 2x10uF??
In general I fully agree, to use a higher input capacitance. My main concern is about the USB inrush current.
By adding series resistance (limiting the inrush current), you reduce the amount of current change once the input cap is fully charged, and thus limit the voltage spike. Similarly, by adding a high-ESR capacitor in parallel to the low-ESR input cap, you get the slower charging of the high-ESR cap, but the fast transient response of the low-ESR cap for the buck converter to be happy.
And finally, as the paper also shows, you can add TVS diodes to limit the voltage.
I understand. The MLCC I am using do have a low-ESR. High-ESR capacitors are Electrolytic Capacitors as far as I know. I am not so familiar with the ESR topic, but issues due to high inrush current I know.
Many boards use a Buck-Converter and allow supply via USB or external connectors. This topic I have never been seen addressed in any of these tutorials.
You might want to consider supporting both the 63203 and the 63200 (adjustable) variants.
I thought about that, but decided against that, as I will supply a specific device (RP2040) with the AP63203. So, I think no need for an adjustable output voltage.

But again, thank you all for your comments and input.