Yep getting a relay to switch >200V at 25A will definitely not be handled very well by any general-purpose relay.
Large high voltage relays use this very trick to combat acring. They have one set of big bulky high power contacts that carry the actual current once switched on, while having a second parallel set of contacts that is designed to move very quickly and far in order to break any arcs that form. So when the relay is opening first the large contacts opens, transfering load to the small contacts that then quickly spring open shortly after.
When the voltages are low enough the 2nd arc resilient contact can be replaced with a semiconductor. But if you are to have AC across the contacts this usually means you will need two transistors in series in order to interrupt each of the directions. Isolated gate drive is also required to turn them on and off while floating, but a simple gate drive transformer should work well for this.
But do also give some thought into what happens if this system fails. With the sort of voltage and current at DC the failiure of the arc supression system could quickly ignite an arc on the relay upon next turn off and keep the arc going as the relay is open, eventually burning through the relay housing, the fire helping sustain the arc even more, melting the relay itself and drawing the arc onto something near the relay continuing the dangerous angry hissing DC spark fire until the entire device is burning.