Yes, you can do that. Be careful, even at audio frequency it can be hard to actually measure -112 dB crosstalk. That is a few microvolts rms. So you scope is not going to cut it, you need a higher resolution instrument like an audio spectrum analyzer. Also, be aware that crosstalk in your measurement apparatus can also show up.
For SNR, the problem is that few instruments have enough dynamic range to show your 1 V signal and the noise at the same time. The normal solution is to use a notch filter that blocks 60+ dB of the 1 kHz test tone, then look at the result on an audio spectrum analyzer.