I'm still glat that it came up.
It is called ALUMINIUM. Please. This is from the urban dictionary:
"How the entire world (except the Americans) say aluminium.
Why?
Because that's how it's spelled."
Not to mention, that PCB is not made from it. It is made from Alumina substrate, which is aluminium oxide.
And having a two layer IMS board (because that is how it is called. Insulated metal substrate) completely against the cause. You need one layer, because it needs to be thermally coupled with the alumina substrate.
Grr. 
Incorrect.
Aluminum is just as correct as aluminium. Our periodic table lists the metal "Al" as "Aluminum". It's not just an incorrect pronunciation.
As for the original question, I realize it's quite old, but MyroPCB and UltimatePCB both offer aluminum PCB's. I haven't done (or seen, actually) a stack up with two layers on top of each other on one side of a metal core PCB, but I have done two sided metal core PCB's before.
For extremely demanding applications, check out Sinkpad. They have a technique where they etch down into the copper then put a dielectric and your traces - this leaves the unetched areas of the coppers at the same level as the rest of your solder pads. And you can reflow the heat tabs of electrically isolated devices directly to these copper pads, which means they are directly connected to the substrate without going through a dielectric.
More expensive than normla MCPCB's but not outrageously so - very useful for highly demanding thermal applications.