My recommendation for anyone that wants to get into casting is to go to home depot and buy a bunch of roofing lead first, then experiment with casting lead.
It is alot safer then aluminum in terms of heat hazard so you can get used to handling molten metal, making molds, using crucibles, pouring metal..
when you get a hang of that then go for aluminum.
I recommend doing open face molds for a while before going to covered molds. My choice is to set sand with sodium silicate and CO2.
Casting is one of those things that seems really easy but if you miss a step or detail you can get injured pretty bad.. for instance if you are casting a closed mold that has moisture in it, you can get aluminum/steam shooting out at you, steam explosions, all sorts of bad shit. Take it slow and actually observe the properties of the stuff you are working with.. I really get a sense here that people are getting too complicated too quickly in this thread for a newbie. Someone just melting a kilogram of aluminum and pouring a complex mold for the first time in their life is asking for trouble.
Watching all of MrPete222's videos about casting is a good primer I think:
https://www.youtube.com/channel/UCKLIIdKEpjAnn8E76KP7sQg (just search his channel for casting).
But seriously start with lead. I studied it alot before I started doing small castings but it was still different because you just feel different when you are pouring a buncha liquid metal, wearing all the safety equipment, feel the heat, etc.