I was curious about DA, so I made simple DA checker, or perhaps more DA experimenting tool.
It consists of two low leakage JFET switches, amplifier with low leakage opamp, plus MCU to switch the JFETs on and off; in order to charge the capacitor to 10V, then briefly discharge it to zero and then leave floating. Opamp amplifier allows observing the capacitor voltage during all phases, especially at the floating one. I abused MAX232 as JFET gate driver.
Attached are pictures of my setup, along with two measurement scope screenshots - one is grey PP capacitor, another one is soviet teflon type. Yellow trace is voltage on capacitor, blue trace is the same, with 10x amplification (plus notice different vertical scale). The voltage rise after discharge is effect of DA, very obvious on PP type, not much significant on PTFE type.
The differences are quite obvious; I tried a few more capacitors, the best were (in this order) teflon, polyester, polypropylene, polyphenylene-sulphide, NP0 ceramic. Worst were electrolytic, high capacitance ceramic were not much better.
Also, I tried different capacitors in my ADC setup. Capacitors with worse DA appeared to provide worse INL; but I have to recheck this again after I finish second version of my ADC.