You have a couple of overall design options: wound transformers or switch-mode.
Wound transformers are heavier, bulkier and more expensive, but are much simpler and galvanically isolate your power supply (safety!). Switch-mode supplies are much more complicated but in general are cheaper and lighter for the power they produce. I presume you are going for the second option.
Designing and making a switch-mode power supply that can deliver ~25V at ~18A (450watts) is not a trivial task and there is no "single-chip" solution for this power level. You'll be dealing with mains voltages, complex switching circuits with large, external switches and possibly extra layers of transformers and rectifiers depending on your design. All of these things have complexities you don't realise at first -- and 450 watts is not a tiny amount of power.
For example: an
ATX power supply schematic. You would be able to cut out about a third of this as you don't need the extra voltage rails, but that's about it. These are designed the way they are to be efficient enough to avoid catching fire (at-least about 65% for even the worst PSUs), small and simple/cheap as they possibly can. You could get away with not meeting regulatory specs (eg line filtering, power phase correction) but that only chops away a few components at best.
If you don't want to do this your best options are to mod an existing PSU, join two as you have suggested or use a large toroidal wound transformer and regulate from there. Notes for these options:
- Modding an exiting ATX PSU -- If you open up several PSUs that can output your desired wattage on their 12V rail, lookup the part numbers on their main switching controller ICs. Modding the 12V rail to output 24V or above may be as simple as changing a couple of resistors and making sure other parts (eg capacitors) are rated to go that high.
- Joining ATX PSUs -- Make sure to isolate (atleast) one power supply from ground. Commonly the DC GND is attached to the case/AC ground, so if you hook two ATX PSUs in series then you are just shorting 12V directly to GND. To isolate a PSU you need to cut traces/parts that you believe are cuplrit and then test to see if this has worked with a DMM.
- Using a wound transformer -- a 1/2 kW one will weigh quite a bit. If you are lucky an old piece of equipment will have one you can steal, otherwise they are pretty expensive, but also the simplest and safest option.
Overall: don't forget that the primary side of power supplies is dangerous. Take your time and think things through.