On the MPC CAN controller chip:
The TxB pins are to allow you to load the controller with CAN data, and send those values repeatedly by pulling those physical lines low. For some applications, which repeat the same messages lots of times, this limits the amount of work the host uC has to do over the SPi bus. However, generally, these are not used, and you simply load the data over SPi, and then trigger the controller to send the data by setting a bit in that controllers register, again, over SPi.
The "interrupt" pin is much more useful and should be used! When a message arrives that matches the internal message mask/filter register values in the controller (loaded from the host uC at initialization), the INT pin goes low to signal a valid message has been received. You then use that interrupt to call a function to unload that message from the controller. If you don't use this pin, then you must continuously POLL the controller to see if a valid message has arrived, which takes up a lot of your host uC time!
It's also important that you promptly unload the CAN controllers Rx buffers when a valid message arrives, otherwise you can miss messages if another one arrives and overflows that buffer (various buffer modes are available, and you can trigger fault flags on overflow etc)
You can use the RxB pins to drive RX / TX leds, which is really useful to show CAN bus activity!!