IIRC there was a thread not all that long ago where someone was complaining about the white solder mask being less well-defined (i.e., nominally rectangular cutouts were smeared/rounded, generally imprecise) as compared to other colours.
Interesting to consider that the colour white is generated by small particle that scatter light. The solder mask is set using UV light. Slightly conflicting requirements, perhaps? In any case, it sounds like the white mask spreads on as a thinner liquid perhaps; leading to poorer edge definition but a more self-levelled, smoother finish. </pure speculation>