Usually by "split power rail supply" people understand that MCU using different voltage on VDDIO and VDDIOB. It is clearly not the case here. This is just a design with multiple power supplies. And from what I see 5V supply only goes to the CAN and it is decoupled from the rest of the system with a transceiver. This is fine.
From a quick look, you are missing decoupling capacitors on the MCU VDD lines.
Microchip has a free design review service. You can submit this there. It is likely to go to me anyway, but I will be able to spend more time reviewing this.