Without knowing the environment, a thick layer of hard gold plating is pretty inert, but I guess it's horses for courses, what exactly are you trying to do? Low voltage mechanical switches have their own unique issues.
Gold = expensive. Trying to keep this fairly low cost. It is for a shop measuring tool. What are the specific issues with low voltage switches are you referring to?
Switches often rely on the “self-cleaning” action of arcing itself. If you run such a switch well below the voltage and current levels that cause arcing, the contacts will oxidize over time and without the self-cleaning, will foul and become unreliable. For these applications, switches with special plating (very often gold) are needed.*
(In contrast, gold is very susceptible to arcing damage, so using a gold plated switch on high voltages will damage it quickly.)
Please share a lot more information about the application so we aren’t tiptoeing around in the dark trying to figure out what to ask you.
*As an example, the microswitches used in many modern wireless computer mice are special switch models because they use such low voltages. This becomes a problem when replacing worn-out switches, because these special switch models are not normal stock items at the distributors. You can easily find switches that are mechanically compatible, but their contacts will foul much sooner.)