To add to what Zero999 posted above, it's recommended that you use the reference voltage for the ADC to create the offset voltage. For example in that circuit if the 3.3V 'ref' net is the reference for the ADC, then all is good. But if the ADC actually uses another reference voltage, then any drift between the two references will show up as measurement error. It's even possible for you to end up with worse accuracy/precision than a simple voltage divider with no offset.
If you tell us specifically what MCU you are using we can give more specific guidance.