The factory trim of the scale factor looks quite good, though there is some doubt they actually get 0.05% accuracy after soldering.
With the additional dividider at the voltmeter input, there is anyway likely a cal factor in the software. It is not that much effort to get the adjustment right.
Yes, so with a 0.05% accurate voltage reference, the max theoretical error can only be as good as 0.05%.
On a 10 volt signal, that means 10.000±0.005V.
With a 30V signal that means 30.000±0.015V -> 30.00±0.02V so much so for those 5 digits

Fully assuming that any additional voltage divider won't attribute (which is mathematically and physically impossible)
This is however without any other additional issues, like gain error, match error and DC offset (as well as drift).
With external components you will makes this error a lot worse very quickly.
According the datasheet, the gain error is 0.05% typical, but can be 0.35% maximum.
Point is, we don't know.
I am a little confused what they mean with the PGA error, since there is only one PGA in there?
Usually this is just (quite literally) just an amplifier stage, which it could mean the gain error in de positive vs negative input.
If that's true, this can cause a lot more issues with a typical 0.1% error.
in 18 bit mode it only does 3.75 samples per second, so you won't be even able to measure 50/60Hz hum.
Any low-pass kind of behavior will automatically mean an averaging filter to begin with.
Only in 12 bits mode you will be able to really measure this 50/60Hz hum.
In the end it's always a little odd, having so many bits with a reference that's only 0.05% accurate.
Meaning that it's fine to measure relative differences very well, but absolute differences you still need an external voltage reference and some calibration inside the microcontroller.
Or in simple words, you can detect a difference in signal very well, but the value of this difference a little less.
(the main reason why most professional multimeters/bench meters are not more accurate as they are)
The contribution of an external voltage divider can be calculated as well.