I have used diodes with SMC package to handle voltages up to 350 Vdc. Check for S3F or S3G or something similar. Some manufacturers add an extra E in the beginning, ie ES3F.
The creepage distance between the pads is dependent of the PCB material and also of the pollution degree inside the enclosure. You can add distance by putting a milling line, with a minimum width of 1 mm, between the pads and let it extend 1.5-2 mm out from the diode package.
One other option is to add some conformal coating to the PCB after the diode is soldered. We used that on a board with 450 Vdc and some SMB package diodes. Some coatings are possible to inspect with UV light to make sure that all areas are covered.
1206 can be used if connected in series. Check voltage and power rating, as some other forum members already noted. Also note the creepage distance between the pads and add as many resistors you need to get the desired creepage, power and voltage rating. If the distance between the pads on a single resistor is 1.5 mm, then you need, at least, 3 of them to get more than 3.5 mm.