When you say "detect" what does that mean exactly?
Do you mean a human visible indicator? Like a pilot-light?
Or do you mean something that can be connected to some electronic system?
If the latter, then these modules are specifically designed and rated for exactly such applications...
IAC5A AC Input, 180-280 VAC, 5 VDC Logic
http://www.opto22.com/site/pr_details.aspx?cid=4&item=IAC5A
The IAC5 input module is used to sense ON/OFF AC voltage levels at 180-280 VAC. All AC input modules are designed with filtering on the input and a hysteresis amplifier for high noise rejection and transient-free clean switching. Each module provides up to 4000 volts (transient) of optical isolation between the field inputs and the logic output of the circuit.
Typical uses and applications include sensing the presence or absence of voltage or sensing contact closures from sources such as: Proximity switches, Limit switches, Float switches, Selector switches, Push buttons, Toggle switches, Thermostats