I would suggest to characterize an op amp, you would measure both its input and output, then subtract the input spectrum from the output. Now you're left with the op amp's spectral contribution.
For the sake of argument, say you have 1kHz bins and want to measure the noise in a 1kHz to 10kHz band, then you add up the magnitudes of the bins, and subtract by the square root of the bandwidth (9kHz), or sqrt(9k) = 30*sqrt(10) = 94.86.
And, good point - the values are peak values, not RMS and usually noise density is expressed as an RMS voltage.
If you measure it across the entire bandwidth of the op amp you get something akin to a Noise Figure.
If you want the noise density from DC, don't omit the 0 bin; the noise can very well have a DC component, and often does when dealing with semiconductors.