I'm comfortable with 120V AC sensing with opto-isolators. A little less so with 240V. Extremely not with 480V. So I want to purchase the two sensors and let our electrician hook them up. Then convert the output (whatever format) to get to logic levels, with proper isolation. I will most likely include another opto-isolation level at this point.
Optos are fine for 480V, as far as I know. If you're building a circuit, just use bigger current-limiting resistors, and more of them. Two metal/oxide film 2W resistors in series, heck, one I think is enough, so two gives you that design overhead. Installed axially, the lead length is more than enough for creepage.
If you have ground nearby, you could even add low-clearance spark gaps, or actual MOVs or GDTs or whatever, to keep the isolation voltage down (you'd then use a resistor or two on each side of the opto, so common and differential voltages stay cool).
If you meant off-the-shelf detector modules or something like that, beats me -- I never played with PLCs and hardware. I'm sure they're out there though.
Tim