See page 9 ("anti-series connection" paragraphs) of this CDE application note for electrolytic capacitors for a discussion of back-to-back connection for non-polarized unit.
https://www.cde.com/resources/technical-papers/AEappGuide.pdf
Here, I'll save people the trouble of downloading that PDF:
If two, same-value, aluminum electrolytic capacitors are connected in anti-series configuration with the positive terminals or, more usually, the negative terminals connected together, the resulting single capacitor is a non-polar capacitor with half the capacitance. When voltage is applied to this anti-series combination, the correct-polarity capacitor gets nearly the full voltage.
I posted the site so that other people could find details about aluminum electrolytic capacitors.
Another important paragraph discusses the voltage capability of the anti-series connection:
"CDE also offers non-polar capacitors in a single can, using two anode foils and no cathode foil. Most motor-start capacitors are
also constructed this way. These are available for momentary-duty AC applications like motor starting and voltage-reversing
applications, but the high dissipation factor of aluminum electrolytic capacitors— often exceeding 2% – causes excess heating
and short life in most continuous AC applications. The reverse voltage capability is not constrained to be the same as the for-
ward voltage, as we can also create special designs that have, for example +400 VDC and -25 VDC capability. This is done by using
two anode foils with different formation voltages."