TOSLINK cables are POF, but really shitty POF. Avago says they can do fast ethernet over 70m NA0.3 POF with their transceiver.
GI-POF can do a lot better than that of course, but I don't know if you can buy COTS transceivers for that. At that point alignment probably becomes just as big a headache as with glass fiber, but bits of fiber not having the ability to outright murder you is nice.