But this time im more interested in using LEDs for sensing their specific (or range of) wavelengths
Anyway did you checked in those experiments influence of light angle relative to front of the led?
I have no idea if it affects its wavelength sensitivity somehow, but it changed output voltage readings for sure at the same lighting conditions in a way I do not expected


LED (3mm THT yello) absorbing sun light at cloudy day pointed directly to te sun covered by clouds gave me ~3 (three) times lower voltage ~100mV in comparision to its maximum ~300mV which I had when it was turned 90 degrees perpendicular to expected sun rays in a way as if sun was on the top on linked image

Cheapy multimeter used probably has ~1M, so this is load resistance, I guess.
Didn't check SMD 1206 green LED yet, but it will be interesting to see If this angle also affects those LEDs output voltage

Looking on yor osciloscope photos you have those diodes put into scope inputs in a way it detects flashes in a way we expect to get highest readings (front of the led), but my experiment showed it might we wrong assumption

If you could rectreate different conditions and show us results at different angles it could be interesting if you have also higher response at suggested perpendicular led axis position vs light source rays.