Just quescent current of mentioned 1MHz GBW LMC6482 dual opamp is 1mA and it shall drive capacitive input of ADC. I would say that at least 10mA shall be available. Your price argument also is kinda shaky because for 0.8$ @100 you get 50mA NCP1729, 4n25 costs 0.42$ @100 (mouser.com)
When I did it I used the low power LMC6462 variant (and later LMC6061 because the LMC rail-to-rail input parts have horrible precision) of the LMC6482 but there is a better way; use the negative bias current to directly pull the output down to and slightly below zero directly. The common mode input range extends slightly below ground anyway and the output does not mind 10s to 100s of millivolts below the negative supply. This of course applies even more so to the 358/324 which only provide an internal 50 microamp pulldown current with compliance limited by Vce saturation but I never liked them for single supply outputs anyway.
The only thing to watch out for is forcing the base-emitter junction into breakdown if you use it but this is not a problem in 5 volt circuits and the base-collector junction does not have this limitation. There are some higher performance solutions but 4N25s are cheap.
There is another way to do the above using just a bipolar transistor to replace the optocoupler but the efficiency and performance is worse so it is not worth pursuing. Many 2N3904s died to provide this information.