The angle between phases is always 120°, regardless of a neutral conductor and regardless of Delta- or Star-configuration. A phase angle refereed to neutral does not even exist.
Yeah, remember though that inversion, aka 180° phase shift, can be done, and is done in every motor, by simple passive arrangement: another winding wired in the opposite direction.
This is how a 2-phase motor (this is what "1-phase capacitor run" motor actually is; this is what most stepper motors are; and this is also the imaginary model used in 3-phase motor control algorithms!) actually has 4 poles capable of generating magnetic field waveforms in 0, 90, 180, and 270 degrees, when supplied with 0 and 90 degree electrical waveforms.
Similarly, when a 3-phase motor is supplied with three phases 120deg out of phase, the simplest possible so-called "1 pole-pair" or "2-pole" (which means 2 poles PER PHASE) motor creates, with its 6 poles, waveforms of 0, 60, 120, 180, 240 and 300 degrees, when supplied with 0, 120 and 240 degree waveforms. And this underlines the mathematical beauty of 3-phase distribution (the thing Nikola Tesla figured out): the angular "resolution" doubles from what you supply. This does not happen with 2 phases, where you create two signals 90 deg out of phase and get four out which again are 90 deg out of phase.
Duak's claim of 45 degrees from a 3-phase inverter I don't buy, but reserve the right to be wrong and corrected here, maybe I'm missing something; I'm only a motor control semi-expert. But 60 degrees is actually a better approximation of the desired 90 degrees than 45 is, so maybe duak meant that one
