There is also a PID loop in software in a small PIC microcontroller that is responsible for maintaining control. Even if you got into the source code of the PIC, it can't do much more. Its isn't a hardware limitation, its a design limitation. The heater, heats the tips through a imperfect thermal interface which has a thermal resistance and lag associated with it.
High performance irons (JBC, etc) have a much more direct thermal connection between the heat source and the tip, Weller's higher end irons have this property too but they cost a lot more. With the thermal design of the PES51 or WE1010, pushing the iron harder will just make it unstable- there is lag in the thermal path and the ramp is slowed down to maintain stability.
I think these types of irons are really perfect for what I do- medium to fine rework on boards, not production. These "direct coupled irons" can pour in more heat than I need at times. I kind of like this higher impedance source of heat- it doesn't get away from me.
I've seen Dave Jones do tests where he is heating up 10 square inches of copper clad- this is a very rare case for me. If I need to do this, I have a 20 year old Weller gun that can put 250W into a solid block of copper. I prefer the control with an Iron like the WE1010- its predictable. The ramp time is part of the trade off.
My personal opinion, open to dissenters.
John