The beauty of transformer balancing is that it's pretty flexible in this regard- this is one of the reasons why some pro audio equipment still uses them.
-One side goes to the hot connection (center of RCA, tip in a TS connector)
-Other side goes to the negative connection (shield of RCA, sleeve in TS connector)
-Center goes to a separate shield on the cable, if it exists, otherwise leave it open. If you're like me and use extra starquad cable for your interconnects, tie the braided shield to the center tap.
Careful about tying the center to one of the two sides of the transformer- this creates a shorted turn. While the transformer might not be damaged (low power level), it will load the driver circuit heavily which will lead to distortion.