I did a TPS40210* SEPIC, in DCM, and it passed almost every automotive EMC test. Layout and filtering is far more critical than operating mode.
The one test that didn't pass, was an extremely sensitive electric near-field test, which picked up a few microvolts from the switch node. A little metal over top is all that was needed. We ended up with a proper RF shield can for production, though.
*Do not recommend. The maximum setpoint is above the current fault threshold. Retarded design. Workaround: remove soft-start cap so that, when it faults during startup, it still delivers enough average current to get going (a few 100 mA). Have a thread on TI E2E that's characteristically unsatisfactory, documenting this behavior.
Tim