Try 3M 44T-A if you want thick margin tape. Highly unlikely that the fishing line is allowable under your magnetics' vendors UL insulation system. Check with them for what insulation systems they have access to, and then you'll know what you can and can't use.
Also, unless I'm missing something from your layer stackup, you don't have to use TIW for both primary and secondary. Often times, use normal enamel wire on the primary and use TIW on the secondary. For a step-down converter, you'll need more turns on the primary, so the extra TIW thickness adds up more. You can definitely do it the other way around too.
You, of course, can use TIW for everything, but your bobbin copper utilization will be much worse, and the cost will be higher.