Now we're getting somewhere. That's not my board, but it's the same. What is C? But it should tie to B, which is the header for the soldering iron. As for E, which is my area of interest, it is an unused header and it looks similar to B. Is this where I can attach an additional soldering iron? I think H & I and the nearby headers support the hot air gun and the pump. So what's A and does it support E like you mentioned? If so, that's an extra unused slot.
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First of all, that PCB is from a Xtronic 9020. It may be the same as your unit, but unless the part number is the same, it's not the same. The board does not have support for a second iron. If you look at the components on the board, what do you have? If there were multiple slots for multiple irons, you would see duplicated circuits, but there isn't anything like that on the board. Look up the datasheet for C. I bet it's a triac since there's a MOC3041 right next to it. A MOC3041 is a zero crossing triac driver which indicates it's used for on/off control of an AC device, not for phase shift. You need to do some investigation with a DMM to see what's tied to what. I can fairly confidently say B-C is not the same relationship as A-E since there's no triac driver near A. There are four power components, likely for: Soldering Iron, Fume Extractor Pump, Hot Air Heater, Hot Air Fan. With the exception of the vacuum pump, all should be variable speed/heat.