Is the goo hard or somewhat soft like hot melt glue?
If it is flexible like hot melt, try isopropyl alcohol. I have best results with 91%, but 70% may also work. Wick a little on, and hot melt releases. It does not noticeably dissolve hot melt, so there is no residue to clean up.
As for the PCB and other components, they are not affected by isopropyl alcohol and most likely not affected by acetone. Acetone is more aggressive and will affect plastics like ABS and styrene.