Probably the bottom pad is soldered to a heavy ground plane.
Set the oven to 150ºC, pre-heat until the thermostat turns off, turn off the oven, wait 2 minutes to let the temperatures equalize, put the board in, take out after 5 minutes and quickly blast it with hot air.
Better to wrap the board with some isolation cloth to keep the temperature.
If you have one of those 2000W heat guns made to scrape the paint off, will also work great, just don't burn the board down!
Apply the heat from 10-15cm in circles around the whole board for 30s-1 minute, then proceed with desoldering.