I think you can calculate the value if it is a filter, but if it is indeed on a DC line (can not open the schematics on this thing I use now) it does not matter to much. But more important it will not cause smoke. I would first try without one, if the synth works then try some values, I would start with 100 pF en su go up to 100nF but I assume you do not have a capacitor substitute box to fast try other values.
BTW, if you plan to do more, it can be handy to buy some caps, to banana busses and a multi position switch and make a little substitute box. (you can connect multimeter probes to it or crococlips) You can use it to AC couple audio in a circuit, set a cap over the powerrail of an IC to test things (for instance to see if the ripple on a powerrail needs replacement, or try to find the best value like in your synth. (You could use something like 100pF, 1nF, 4,7nF, 10nF, 47 nF, 100nF, 470 uF, 1uF, 10 uF, 100 uF and 1000 uF)
You can also make one with some resistors so you can limit currents, bleed capacitors, make a filter together with the caps-box.