No worries pbarton! Any ideas whatsoever are welcome...

I've just done another small bit of investigation of the system this afternoon, and I think I've figured out what's wrong.
The original problem, was an intermittent failure to ignite the fuel. After 3 or 4 attempts, the Red fault LED would come on. One evening when the system had just switched off normally, I heard this clicking noise coming from the controller,
and thought I was on to something, but it turns out that this left relay is not needed in my setup, due to the way the electrician originally wired in the Wall-panel and the water pump.
The PCB in the picture is actually a 2nd-hand one I bought as back-up/spare, but this one turned out to have even more issues that the original board...! (When the rocker switch on the spare PCB is turned on, it brings on the red fault LED straight away. All power rails are smooth, CLK signal to uController is good, and I resoldered all pins of uController. Might be corrupt software or something??

)
The PIC only controls the Ignition element relay. The other relay is hard-wired to the main DC rail, and even continues to get power when the rocker switch is switched from the On position to Standby/Off. This relay only ever de-energizes when the power-cord is pulled.
Anyway, I used a Power-Meter to check the consumption during the ignition sequence. Then I installed a brand new ignition element, and re-measured the consumption. Even though the new element was rated 420w (v's the original at 425w), the new element used on average 3% more power than the original, so there may have been an issue with the old element. This may help explain the intermittent startups. Trouble now is that I accidentally scratched the new element against its metal mounting, and now the RCD is throwing a hissy-fit, so I must order another replacement
element.
The other issue I found was in relation to the second fan. I had already cleaned the blades of the ignition blower, but for the flue-fan I only did a really quick rough-and-ready clean. When I fully opened up the flue-fan casing I found that most of the small blades had heavy deposits on them. The negative pressure in the flue would have suffered due to this, and the air-channel back to the igniter and blast-tube area may not have had enough of a draught to facilitate ignition. I did a thorough clean of this second fan, so hopefully that will help matters.
So all in all, I think it was two separate marginal fails combining together to create an intermittent fault, all the while the unused relay clicking away randomly just to confuse matters!
I don't have the electronic schematic for the PX-21 control board, but I do have the system wiring diagram from KMP, the Swedish manufacturer of the Burner section of the system. See pic attached.