Aside from a donor unit, probably some generic patching epoxy/regluing existing pieces will probably give you the best treatment. Basically, you don't want to use too much extra material because additional weight on the key will effect the feel of it while playing. It also doesn't generally need to be that durable (current damage I can't imagine is common....), so the most important thing is getting something back in there and then making sure it is sanded and buffed smooth to match the height and feel of the surrounding bits - it will absolutely be noticeable to a player if there is inconsistent texture on the surface of the key, so my advice would be to match the finish as closely as possible and to use sort of whatever works for the actual patch.
You may be able to find keytop stock for regular pianos - it's generally wooden levers with plastic fake ivory on top or similar - but because the thickness of that is molded into the key you have, to use it and maintain height with other keys, you'd probably need to cut/sand off most of the key top that you have, and then glue the replacement top to the remaining plastic frame.
If you can determine the plastic, it's also worth mentioning that a plastic cement will probably give you best results if one can be found.