I usually don't change electrolytics as a matter of course unless I see leakage or there is excessive ripple on a particular power rail. With the 465, you are more likely to have problems with the tantalum capacitors which will short and bring the rail down near zero. Make sure you check the power supplies with a scope, not just a DC voltmeter.
Also with these scopes, the pots and switches will need a thorough cleaning with your favorite contact cleaner. Be prepared to dissect the two attenuator cam mechanisms and clean the spring contacts with alcohol.
As is the case with many vintage Tektronix scopes, disassembly is a bit of a chore, but everything is logically organized.