I have been pulling my hair out for the last week trying to figure out why my -12V Rail (Pin 14) is -9.39V, and the Pin 8 is .123V. Also on the 10 Pin Molex no# 2 pin is 11.4V when it should be 2.7 according to the service manual and the Pin 5, and 10 are 2.47V and 1.84V when they should be 7mVrms.

I've changed all the capacitors on those traces and it hasn't helped. I figured that a bypass cap might have went belly up but that doesn't seem to be the case. All the caps I replaced checked out in spec. I never new that an ATX would be such a pain. I have considered swapping this PSU out with a solid Corsair VX550 PSU but i haven't because I'm not sure what the 10 pin molex does and it's connected to the PowerPC board.
Also, while repairing this unit, I first had to replace a mosfet and .025 SMD resistor on the PowerPC board and that resistor and mosfet are by the 24 Pin connector. I plugged the scope up when I first received it, and the 945G (Advantech) motherboard wouldn't get past the splash screen, so I changed out the caps on the motherboard and tested it with the above mention Corsair PSU and got it work properly. Now the PSU is the only thing that is holding this up.
I had 2 of these scopes with the same issue. The first one is working like a champ after replacing the caps on the 945G motherboard and recapping the PSU. Now this one is giving me the Willies.
I have a theory but it's just enough to be dangerous. I think the problem might be in the PFC circuit, but I don't know enough about it to know what exactly to look for. Not a SMPS kinda guy, but I'm learning quickly that I have to be one.
All the other voltages are in spec. One last thing, is the 10 Pin Molex for PFC? It's seems to be so because the 7mVrms pins 5, 10 are linked to the mains Live and neutral and are color matched (Brown, Blue), but they are only shrink wrapped to the lines so there's no physical connections at all. I've read some where that this is to get a sine wave for VA or something or another. I'm assuming that this is part of the whole PFC thingy.
One last note, When I was testing the PSU standalone, and put a load on it (8ohm 20 watt resistor on the +12V line, the PSU cut off. That's only a 1.5A load so I know something is screwy somewhere. I'm starting to think that it it one of the ICs (Dips).