Ok you got it fixed, yeah most every pin of the PS223 is behind some resistor and/or capacitor network, and the max voltage of anything on the secondary side is maybe 13V at the transformer output before the rectifier diodes. So it's probably hard to damage the chip, most pins anyways.
The 12V aux voltage, it comes from the same transformer that makes the 5Vstby. That's usually run by a little 8-pin switcher chip. If the supply is plugged in, and the switch on the back of the PSU is on, and there's no problems, then the little 8-pin switcher should always be running. But that 12Vaux voltage is kept away from the CM6800, with a BJT or 2, and an opto-coupler, until the PSU-on button on the PC is pressed. That tells the PS223 or some little circuit around it, to open or close the opto-coupler, and some BJT, which then allows 12Vaux to reach the CM6800 Vcc pin.
If the CM6800 doesn't have a problem, I think both gate drive pins should be running. Sometimes under low loads, like no computer hooked to the PSU, it might not run the boost drive?? IDK, I should learn more about these chips too. A lot of these switching regulator chips, and controllers, will have low power /idle modes, where they run at a lower frequency, or burst-mode, where they run for a little bit, then wait for a little bit, and repeat.
The PS223 or similar chip, usually can run from 5Vstby, but uses the main 12V output rail for power, once that's up and running.