Further information on temperature-compensated zener reference diodes:
Motorola made these devices with three choices of the number of forward-biased diodes in series with one reverse-biased zener junction:
1 diode: usual total voltage of roughly 6.2 to 6.5 V (depending on zener construction and operating current).
2 diodes: usual total voltage 8.4 to 9.1 V
3 diodes: total voltage roughly 11.7 V
Zener (actually, avalanche) diodes above 5 V have a positive temperature voltage co-efficient, and the forward-biased diodes have a negative temperature co-efficient, so with an appropriate current the absolute co-efficients (V/K) cancel and the total voltage is constant.
To obtain this cancellation, the device current must give these co-efficients. The sorting of devices (e.g., 1N821 series) into tempco bins actually represents how close the appropriate current is to the specification current (7.5 mA for 1N821 to 1N829 series). Back in grad school, where graduate student labor was cheaper than precision parts, the lab next door would buy the cheapest 1N821s and find the appropriate current for each unit to achieve zero tempco, using a Fluke differential voltmeter and a lab oven.