OK, I do know what's different between RT and RT-MS cartridges.
RT-MS has a separate tip ground on that cylindrical part going into the handle. 3-contact jack pin closes to the tip is NOT connected to the tip as it is in plain RT cartridges. However this difference is superficial -- RT-MS has a PLASTIC washer covering that cylindrical part opening towards the handle that is not conductive so those two contacts are not connected. Plain RT has a METALLIC conductive washer instead that simply shorts those 2 contacts. I didn't try it but would bet that removing that washer will make RT-MS from RT.
There is also some mechanical difference -- RT-MS has additional thin metal tube with nicely engraved "RT-xMS" and "Weller" over that bare tube piece between the handle and beginning of the heater. I'm almost 100% sure it only serves decorative purpose, nothing else.
Difference in the handle (if it exists at all) is that zero ohm resistor to pin 5 is removed and pin 5 is connected directly to the tip. That would've allowed that fancy 3.5mm "Ground select" jack on WR3M to actually do something (provided nothing else is connected, just WMRP-MS.) If anything non-MS is connected that jack is purely decorative as that "anything" shorts pin 5 of all 3 connectors to station ground and "grounding jack" makes no sense at all.
I did also a quick teardown of WXDV120 desoldering iron to find out what is that their "totally digital" about. That was total shock as there is actually nothing "digital" in there except PCA9553DP/01 4 LED Blinker with I2C control, 3 LEDs, couple of resistors in voltage divider arrangement (it is probably that "digital ID"), small motion sensor (spring or ball type, much worse that common SW-18010P with a spring) and that's all it has for "fully digital". There is no memory of any kind in the handle. Unless they have something built into their homebrew overmolded connector (I seriously doubt they have -- I've bought a replacement WXP200 cable from Amazon for $8 specifically for teardown purposes and it is original Weller part in their packing having just straight 6 wires, nothing else -- all that "full digital", "stored calibration" and so on is even bigger lie than Volkswagen diesel emission data...
I do also have several plain DXV80 irons and they are almost identical to that "fully digital" one, also having 6 wires and a simpler board without LEDs, PCA9553 I2C LED Blinker and motion sensor.
Also have brand new WXP200 iron and there is nothing "digital" there too except the same parts that are inside WXDV120 iron. BTW, I do also suspect they made 120W desoldering iron off of 80W DXV80 by merely replacing "80" with "120"

There are chances I might be wrong and overlooked something but they are slim. I'm 60 y/o professional Electronics Engineer doing this for living my entire life.
Just to be sure I've purchased a WX2 station to actually hook up a scope (and LA if there IS something digital) to find out what's going on between an iron and the station.
However it looks almost certain that their WX series only standardized irons pinouts so they could throw away that extensive probing/switching circuitry present in WR3M and added blinking LEDs where it was possible (not in WTP90/WMRP/WMRT) and motion sensor switch.