Hi,
a DC block will not protect from static electricity.
It is used, to keep DC away from the SA input, hence the name.
The SA has a input impedance of 50 Ohms (normally). Any voltage will be shorted to ground via 50ohms.
If you want to measure rf on top of a DC voltage, for example to check the purity of a DC power supply, you will damage the input of the analyzer, because it can not dissipate the power from the DC shunted via 50 Ohms to ground
Chris