Imn is so called coupling integral and in this case 'mn' are not indexes seen in usual mode numbering convention such as TEmn (if that confuses You), but instead m is index of all possible modes in waveguide with dimension 'a' and n is index of modes in waveguide with dimension 'c'.
In case of H plane step and TE10 excitation only modes TEx0 = TE10, TE20, TE30,... are excited, so 'm' indexes modes TEx0 in waveguide a and 'n' indexes modes TEx0 in waveguide c. The Imn theoretically has to be evaluated for all possible mode couplings, but truncated to N terms in practice like this (prefix '_a' and '_c' identifies waveguide with dimension a or c):
I(TE10_a, TE10_c) I(TE20_a, TE10_c) I(TE30_a, TE10_c) ... I(TEN0_a, TE10_c)
I(TE10_a, TE20_c) I(TE20_a, TE20_c) I(TE30_a, TE20_c) ... I(TEN0_a, TE20_c)
I(TE10_a, TE30_c) I(TE20_a, TE30_c) I(TE30_a, TE30_c) ... I(TEN0_a, TE30_c)
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I(TE10_a, TEN0_c) I(TE20_a, TEN0_c) I(TE30_a, TEN0_c) ... I(TEN0_a, TEN0_c)
Term I11 here is first term (or N = 1) in the coupling matrix or coupling between the TE10 in waveguide 'a' and TE10 in waveguide 'c'. Of course, You should use N >> 1 to for solution to converge.