I've never used one. From what I know, they were designed to do measurements as would be done in semiconductor fabs, like verifying processes. As for what a hobbyist could use it for, I guess as a limited voltage source that can do steps and square waves, and ammeter. It goes down to 20 pA full scale with 1 fA resolution. So it's probably quite good as a high resistance meter: 20 V / 20 pA gives 1 TOhm full scale, with a resolution (surely down in the noise) of 1 POhm.
I don't know how useful a "quasistatic C-V curve" is outside semiconductor device testing.
Maybe it could be used to trace I-V curves, like a two terminal curve tracer?