there's no black & white answer...
The Xs has had 5 generations (Xs without LBUS, Xs with LBUS, Xs-A, Xs-B with PS/2 ports, MXs-B without PS/2 ports).
To my knowledge, Xs and Xi shared the same h/w platform.
I think 2.5GS/s for a 64 models only existed for models without LBUS (serial < LCRY0310xxxxxx). 104 models had the same acquisition h/w (as a 64), but... the FE board was physically different (a bit wider, leading the power button to become rectangular, and not square), and attached differently, so the acquisition board for the 104 (and also 204 for the Xi) was physically different from the acquisition board on the 24, 44 and 64 models.
edit: my bad, not really familiar with the Xs, it was indeed 4 x 2.5GS/s, which could be interleaved to 5GS/s on the 104Xs. No clue whether this was a software-based limitation or if the ADCs were indeed different from those on the Xi series ?
So, to come back to the original question: no, the 64Xs is NOT upgradeable (as for the bandwidth).