Aiming the camera on surfaces and getting low/high emissivity is a bit clearer for me now. One thing I'm curious about is placing my hand in a black (Hefty) trash bag and the camera seeing it. I even put space between the bag and my hand, and the camera still saw it.
A black body object is not necessarily visually black!
You have to understand that thermal cameras operate in a completely different part of the electromagnetic spectrum as human eyes do. At the same time the optical properties of a material is a continuous function that goes from radio waves all the way to gamma rays. Our human eyes can only see the narrow part in the middle called visible light.
Just because a material is reflective at one wavelength says nothing about it being reflective at another wavelength. So it is perfectly possible to make a paint that looks white to our eyes, but looks black under IR light. Or the opposite a black paint that is actually very reflective under IR light.
A good example of this is the black IR windows on TVs and TV remotes, or also seen on IR LEDs or IR phototransistors. It is a plastic with a dye in it that absorbs visible light, but is completely transparent to IR light. Similarly Coca Cola looks black to our eyes, but it looks as transparent as water in IR (you can try shining a TV remote at a camera trough a bottle of coke). Note that this is short wavelength IR of around 900nm that IR LEDs can produce. Thermal radiation is even longer wavelength IR at around 10000nm, hence something transparent to short wavelength IR is not necessarily transparent to long wavelength IR. For example water or common window glass is transparent to 900nm IR (so your TV remote works trough it) but LWIR does not go trough it at all, so a thermal camera can't see trough a glass window at all. If we take this even further, going down to a 1 000 000 000 nm wavelength you get radio waves, some materials pass radio waves just fine, some don't, and it has nothing to do if the material is looks black visually.
So your black garbage bag to LWIR likely looks as transparent as a transparent plastic bag.
So you can't rely on your human vision to tell things apart as they cover only a small range of the spectrum. Heck even within that spectrum they have flaws as we can only see in in R G B. So to our eyes yellow light looks identical to a mix of red and green light. There are some humans with a genetic mutation that gives them a 4th color receptor, these people can tell apart some colors that look identical to everyone else.